Refinery fires: Firefighting strategies and tactics
Refinery
fires: Firefighting strategies and tactics
Petroleum refineries
are most hazards industries due to their characteristic of handling, processing
and storing different types flammables materials at or above flash point and
ignition temperature. There are number of hazards including flammability,
toxicity, explosion, physical hazard, noise, ergonomics, electrical hazard,
etc. (To know more about types of hazard, click here)
Amongst all the type of hazards, fire, explosion and toxicity hazard
are the major concerns in the petroleum refineries. Petroleum refineries fire
and explosion can cause massive damage to company installations, loss of life
and health hazards to the neighborhood.
Although there are many different hazards in oil refineries
but this article provides a detail knowledge on firefighting strategy and
tactics for fighting refinery process unit fire, heat exchanger fire, heater fire, furnace fire, vent fire, sewer
fire, oil terminal/gantry fire, oil tanker fire,
storage tank fire, LPG fire, Natural gas fire, etc
Fire hazards in petroleum refinery
Petroleum refinery
inherently possess high risk of fire and explosion due to processing and
storing highly flammable material. Crude oil is blend of number of hydrocarbons
itself hazardous due to its flammability property and toxic
contents. In refinery process, the high temperature and pressure adding the
risk. Petroleum products are handled in pipeline, exchangers, pumps, vessels
and columns at or above their autoignition temperature, thus in case of any
leakage, immediately catches fire.
Gas like hydrogen is highly flammable, only 0.019 mJ ignition
energy required to fire or explosion. All the hydrocarbon vapors are heavier than
air and forms vapour cloud, during leak may cause explosion after getting
ignition. As per Lewis and von Elbe, minimum ignition energy required to ignite
vapours of hydrocarbon like butane, propane, motor spirit (gasoline) and gases
like methane and ethane is about 0.1 mJ.
There are explosion hazards in exchanges, reactors, furnace,
columns and vessels due to high temperature and pressure.
During refinery maintenance or catalyst replacement work,
there is always risk of pyrophoric fire due to traces of ferrous sulfate
formation.
Hydrogen sulfide is deadliest gas in petroleum refinery due
its characteristic of flammability and toxicity.
Bulk storage of crude oil, finished product like motor spirit,
diesel, ATF, kerosene, ethanol, intermediate products and highly flammable
liquefied petroleum gas (LPG) adding the risk of fire and explosion in oil
refinery.
Other fire hazards are electrical equipment, appliances,
cables, oil field transformers, coal or fuel in captive power plants, UPS
batteries, open flame in refinery flare, hot work inside refinery operating
units, etc.
Below are the special fire and explosion hazards in oil
refinery
Boiling Liquid Expanding Vapour Explosion (BLEVE): It is an explosion of
container (sphere, vessel, tanker, cylinder, etc) containing flammable
liquid/liquified gas caused by over pressurization due to boiling of the liquid.
This usually occurs due to the prolonged heating of the container and liquid/
liquified material reached at its boiling point, therefore the conversion rate
from liquid to vapour is higher than the
release rate through safety relief valve/ vent, which increases the pressure
inside the container. In addition, when the liquid converted to gas, it expands
and creates more pressure inside the container, for example, expansion ratio of
LPG from liquid phase to vapour phase is 1: 270 (i.e. 1 liter of liquid
expands to 270 liters of vapour/gas).
BLEVE |
These three factors resulted in a catastrophic rupture of
container and the pressurized flammable vapour released suddenly in the form of
massive explosion called BLEVE.
A secondary fire in nearby facility can be caused by shock
wave and propelled pieces of container.
Unconfined vapour cloud explosion (UVCE):
It is a delayed explosion of released flammable vapor/ gas away from point of
leak source after the formation of flammable mixture in an unconfined area.
UVCE occurred when flammable gas released into the atmosphere,
after some delay, forms a vapour cloud and ignited by ignition source away from
its point of leak source resulted into deflagration.
In UVCE, the flame propagate at an ultrasonic velocity thus
produces shock waves and destroys the entire installation covered under the
cloud.
A secondary fire in the facility can be caused by shock wave
and direct contact of fire and explosion.
If the gas is heavier than air (LPG, vapours of gasoline,
diesel, kerosene and other hydrocarbons), the flammable cloud covers more area
whereas lighter gas (hydrogen, methane, etc) forms less flammable cloud because
it disperses easily.
Flash fire: It is the ignition of flammable
vapour/gas mixture within its flammable range immediately after it’s released
from the source. This type of fire doesn’t cause an explosion, but the flame
burns back against vopour cloud.
Pool fire: Spillage of flammable /
combustible liquid forms pool on surface and ignites by an ignition source,
such fires called as pool fire. It is surface fire in vapours of liquid. The
flammable liquid layer can be on the direct surface of the ground or float on another
liquid such as water.
Jet fire: The release of gas, vapor, or liquid
from the container above atmospheric pressure and causes a fire due to
ignition, called as jet fire. It is a 3D fire in the form of a jet.
Boil over: Boil over is a violent eruption
of viscous liquid such as crude oil from the storage tank due to an extended
fire scenario.
Boil-over in crude oil storage tank |
Due to the prolonged fire in storage tank of viscous oil such
as crude oil, the lighter product pushed up whereas heavier product pushed down
due to density difference in the form of heat wave. The temperature of hot oil
is approximately 350 degree Celsius which forms the heat wave and travels
downward at a speed of about 15 to 20 inches per hour. When this heatwave
reaches the bottom of the tank, it heats the water available there. The water
get boiled and converted into steam, as the water to steam conversion ratio is
1:1700, the steam pushing the oil in the form of bubbles but viscous fuel
resists to release it from its surface and thus building tremendous pressure. The
steam gives a piston effect and finally it erupted with large volume of liquids
and forms a fire ball. The erupted oil spreads beyond the dyke wall and causes
secondary fires. This event occurred several
hours after the combustion of oil in a storage tank.
Slope overs:
Slope over in oil storage tank |
Fire due to spontaneous ignition: When
pyrophoric material exposed to air, it starts burning without any external
ignition source, this fire called as fire due to spontaneous ignition.
During shutdown activities in refinery and petrochemical,
pyrophoric material (iron sulfide) can be found accumulated at inner surface of
equipment, columns and vessels handling oil with sulfur contains. When it exposed
to air, spontaneous ignition occurs even at low temperatures.
Ground fire due to refinery flares: During
process upset, a heavy load of hydrocarbon vapours is diverted to the flare
system, knock out drum (KOD) gets
overfilled with condensed liquid as well as water seal system can be failed
thus liquid reaches at the tip of the flare and burning liquid spreads near the
flare area causing ground fire.
Fire safety in refinery and petrochemical
industries
National and international standards
are available for refinery and petrochemical fire safety systems which provides
the detail guideline on designing and installation of complex. Modern
technology provides the PLC base safety systems including various interlocks,
blow down system, venting systems, etc.
There are two types of fire safety
systems, passive and active. Passive fire protection system is as-built system
which prevent the occurrence of unwanted events or minimizes the consequences
without much human intervention. Active fire safety system may be automated or
manual and comes into action after the occurrences of event. Typically, passive fire safety system is for prevention and active fire safety system is for
protection.
Refinery fire protection system
Refinery fire protection
system is broadly divided into
two category, passive and active.
Typically, passive fire
protection system is provided to protect the system or structures from
failure, for example, fire proofing of steel structures, columns, pipe rack,
vessels, etc. Separation barrier or fire
wall is provided to prevent the spread of fire and to protect the nearby
facility/ equipment from thermal radiation.
Dyke wall around the storage tanks is
also an important passive fire protection system in
oil refinery. Dyke wall is provided for storage tanks to contain
the leaked oil. Compartmentation provided in building area to prevent the
spread of fire and smoke. Trip interlock is also one of the types of passive
fire protection system provided in process units for various systems and
equipment to safely isolating or shutdown the equipment. It is also provided in
HVAC system to activate the dampers.
Active fire protection
system is broadly divided into
four categories and can be used to control the fire, extinguish the fire, and/
or provide exposure protection to prevent domino effects. Active firefighting system
in oil and gas industry is maintained by dedicated company fire
department.
1. Portable firefighting
equipment: It includes portable
fire extinguishers, fire buckets, hose reel, foam trolley, etc. Adequacy and
placement can be done with reference of NFPA-10.
2. Fixed fire protection
systems: here are the fixed
fire protection systems widely used in refinery and petrochemical industries.
2.1 Water based fixed fire
protection system: It
includes, Fire water pumps with fire hydrants and fire monitors, medium
velocity water spray system (MVWS) for exposure protection, high velocity water
spray system (HVWS) for extinguishing the fire, sprinkler system is for
exposure protection as well as extinguishing the fire, fixed foam injection and
pouring system, water mist system, etc. Deluge system is not a separate system,
it is component of water spray system. Deluge valve is provided in water spray
system to activate the system automatically or remote manually. API 2030 provides the detail guideline on water spray system.
2.2 Clean gas fire protection fixed system:
It can be total flooding type or/and local application system type. These
systems are suitable for protecting control rooms, satellite buildings,
generator rooms, battery rooms, cable cellars, etc. NFPA 2001 provides detail guideline of clean agent fire extinguishing system.
2.3 DCP based fixed protection system: This
type of system can be used to protect transformers, electrical motors and
pumps, hot oil pumps, reactors flanges, heat exchanger flanges and other hot
equipment where application of water is restricted to prevent thermal effect.
2.4.
Fixed steam fire protection
system
This type of system can be used to
protect the flanges of hot oil handling equipment, vessel and columns like
reactor flange, exchanger flanges and hot oil pump flanges where application of
water is restricted to prevent thermal effect.
2.5 Rim seal fire
protection system: It is a
fixed type automatic fire protection system intended to protect the rim seal
area of the floating roof tank, the detection ring and the foam pouring nozzles
are placed between the primary and secondary seal of the floating roof and foam
modules are mounted on the roof. The fire is detected by the detection / sensor
ring and activates the foam modules, so the foam is poured between the primary
and secondary ring and extinguishes the fire at its incipient stage.
3. Semi-fixed fire protection system: This type of system has fixed piping but requires
supply of fire extinguishing media from external sources, for example, the foam
pourer system on floating roof and fixed roof storage tank have fixed piping
with collecting head at outside the dike wall. In the event of a fire, fire
vehicles are used to feed the foam solution into the system in order to apply
it to the surface of the hot oil in the tanks or in the area of the rim seal of
the floating roof tank.
4. Mobile fire protection system: It includes fire engines/ tender (fire trucks),
Trailer mounted pumps, Trailer mounted high-volume long-range monitors, Trolley
mounted DCP units and foam units.
Fire trucks are of various type like
Foam fire tender, water tender, water bowser, Foam nurser, Combine fire tender,
crash fire tender, DCP fire tender, etc.
Firefighting strategies and tactics
Refinery Process unit firefighting method
Without
isolating the source or cutting off the fuel supply, it is very difficult to
extinguish refinery process unit fires. Starvation (elimination
of fuel) is the best technique to fight process unit fires.
This can be achieved by making operational changes to
reduce the flow, volume and pressure. Steam can be introduced in the affected
systems or equipment to minimize the fuel concentration and by blow down the sections
of the unit as required.
Appropriate and effective firefighting method,
strategies and tactics should be decided taking into account the location,
type of equipment on fire, process parameters, type of fuel and the intensity
of a fire.
Small fires can be fought with dry chemical powder, CO2,
steam or foam depending on the type and class of fire.
Water in the form of spray is most effective on large
area of intense fire which threaten to damage support structures and adjacent
equipment. However, the use of water may cause flanges and joints to leak due
to thermal shock and my responsible for adding fuel to the fire. Adjusting the
water stream to spray or fog will reduce this danger.
Note: Foam should only be used if it can cover burning fuel
or leaking hydrocarbon liquid / which has spilled on the ground, i.e. a pool
fire.
You may interested to read more on Basic process control system and SIL calculation
Click here to read other article - Layer of protection analysis (LOPA)
Refinery Exchanger and transfer line firefighting techniques
In most cases, exchanger and transfer
line fires are the result of abrupt changes in process parameters viz temperature
and sometime pressure too. Therefore, make an effort to restore the normal operating
temperature of the equipment.
Heat Exchange fires |
Apply steam or DCP or both together to
the point of leak to extinguish the fire. If the fire cannot be extinguished using
portable equipment due to accessibility problem, use DCP fire tender (DCP fire
engine).
Apply water spray to the immediate
vicinity of the leak to prevent fires from radiant heat. The deluge water spray
system can be used to cool the nearby structure and equipment, but the decision
should be made in coordination with operations manager. However, the use of
water can cause flanges and joints/seals to leak due to thermal shock and may
responsible for adding fuel to the fire.
Inaccessible pipe rack, structures,
and other nearby equipment including vessels and columns that are not provided
with fixed water spray system and exposed by flame impingement, can be
protected by applying water spray from ground fire water monitors and handlines.
Fire water monitors and hand line nozzles should be in spray mode.
Apply firefighting foam to the
ground/trenches where burning oil may accumulate. To prevent the spread of fire
in the sewer drain, it should be immediately covered. Avoid working above sewer
drains or near fire traps as there is a risk of explosion.
Maintain adequate drainage of the fire
area and must notify the waste water treatment plant of its preparation.
Firefighting strategy for open Relief valve vent fires
Extinguish the fire by applying Dry chemical powder (DCP). If there is evidence that a relief valve has opened
and will not reset, shutdown the equipment ie. take the equipment out of
service and depressurise it.
If the liquid hydrocarbon overflows from
the vent, apply high pressure water fog/spray working upwards from the lowest
flames.
Apply water spray to the entire
structure engulfed in the flame to the point of advantage around the base of
the structure to avoid heat damage to structural elements.
Electrical Machinery firefighting method
Machinery on fire must be switched off
and start the standby machine, if possible. Apply carbon-dioxide or DCP to
extinguish the fire. Do not use water or fire fighting foam as it may cause
electrocution. De-energise the circuit, if possible.
Refinery Pump and compressor firefighting strategies and techniques.
In case of fire in oil pump or
compressor, equipment should be shut down and immediately changeover to standby
machines. Equipment should be drain out and depressurised the connecting lines,
if conditions permit.
Apply steam or dry chemical powder
(DCP) from portable extinguishers to the point of leak to extinguish the fire.
If the fire is large and portable extinguishers are inadequate to fought the
fire, cover the fire area with water spray and direct the jet of high pressure
water on the source of fuel until the operators have succeeded in stopping the
flow of fuel.
Apply firefighting foam to the
ground/trenches where burning oil may accumulate. To prevent the spread of fire
in the sewer drain, it should be immediately covered. Don’t work above sewer
drains or near fire traps as there is a risk of explosion. Maintain adequate
drainage of fire area.
Use deluge water spray system for
compressor area to protect the structure from failure. Operate HVWS for
firefighting of oil pumps.
Refinery furnace header or tube rupture firefighting method
A header box fire is normally the
result of a radical operating change. Injection of steam into the header box
will usually extinguish a fire. If it is of significant size and cannot be
extinguished with steam, this fire must be treated as a tube rupture fire.
Tube rupture firefighting technique
Preference should be given to removal
of hydrocarbon by isolating the supply fuel and depressurise the system. Inject
steam into furnace tubes, fire box and header box to inert the atmosphere. Fire
can be extinguished by application of dry chemical powder which also help to
avoid the reignition.
Water sprays can be used to protect the
structural members outside the fire box threatened by flame. As the
firefighting foam is ineffective, do not use it.
Trench or Pit Firefighting techniques
Priority should be given to locate and
stop the source of leakage into the trench or pit. Apply steam, CO2 or dry chemical
powder to the fire area to extinguish the. If this is not successful, apply medium
expansion foam to cover the area faster.
Nearby structures and equipment must
be protected by operating the water spray system. In absence of fixed water
spray system, use high pressure water spray from fire engines or use water
monitors in spray mode.
Avoid overflowing trenches or pits
with water since this may cause spread of fire. Don’t allow any person to work near
fire traps.
Refinery sewer firefighting method and tactics
Fighting sewer fires in refinery is
challenging as there is always a risk of explosion. This type of fire can
affect many process units as they may be connected internally though sewer.
During the explosion, covers of the sewer manholes can blow out and damage the
neighbouring facility.
Steam lancers should be used to inject
the steam into the sewers. Other steam hoses can also be directed to sewer
outlets in all gaseous areas. All working peoples and emergency personnel must
ensure that no one is standing or working on or near the manhole cover and sewer
outlets.
Remove the manhole cover at farthest
point to release the built-up pressure during application of dry chemical powder
from manhole where the flame is visible. High expansion foam can be injected
from sewer manhole to extinguish the fire. If foam injection is not possible
then direct the water streams into affected trenches to maintain flow.
Refinery firefighting strategy and techniques for oil spill fires
Many vessels and equipment in refinery
are mounted aboveground on steel structure platform. The underneath of these
equipment, there may also be other equipment handling flammable materials.
Oil spill fires - above ground level
The source
of leak must be identified and isolated immediately as early as possible.
Equipment should be shutdown, isolated and depressurised to prevent further
leakage and to prevent the addition of fuel to the fire. It can be purged with
steam if possible.
A small fire can be put out by applying dry chemical
powder. Steam lancers can be used, if available.
The deluge water spray system should be used to
protect the structure and nearby equipment against radiation heat. In absence
of deluge system, water can be applied by fire water monitors and fire hydrants
in spray mode.
If an oil leak forms pool at above ground level in oil
catch pit area or forms pool at ground level, then firefighting foam must be
used to extinguish the fire. Keep in mind that foam is ineffective on 3D fire.
If there is pool fire or surface fire, foam may be applied.
Oil spill fire - ground level
The source of the leak must be
identified and stopped immediately. If the leak could not be stopped and
continue, then system should be shut down and affected part of the system must
be put out of service. This affected part of system must be drained,
depressurised and purged with steam.
To put out the small fire, steam or
dry chemical powder can be used immediately. If the fire spreads over a large
area, apply the firefighting foam on pool to blanket it. Foam is the most
effective firefighting agent to put out the pool fires.
There may be a risk of fire spreading
in the trenches and pit, foam may be applied to control these fires. The nearby
steel structure and equipment must be protected from radiation heat by the application
of water spray. Water spray can be applied via deluge system or fire engine or
ground water monitors or hoses with nozzles. Flooding of fire water can be
prevented by maintaining adequate drainage of the fire area.
Firefighting strategy for refinery laboratory fire
This type of fire requires different
combating procedures because of glass- ware and special types of apparatus and
equipment involved.
Use carbon-di-oxide, DCP portable
extinguishers on small fires.
In case of large spills of flammable
material whether ignited or not, evacuate personnel from the building and cut
off fuel, air gas and electrical services to the building. Cut off any other
outside source of fuel.
Use water fog or water spray only on
fires, which threaten damage to the building structure.
All fire responders must ensure
self-content breathing apparatus. Entry is restricted in smoke-filled area
without appropriate respiratory protection. Laboratory supplies include many chemicals
which may emit toxic vapours when exposed to fire.
Firefighting strategy and tactics for fighting storage tank fires
Oil storage tank firefighting strategy |
Before attempting to extinguish the fire
in the oil storage tank, fire in the surrounding area i.e. in the dyke should
be extinguished first to prevent heating of stored fuel.
To know more details about
firefighting strategy and techniques for large diameter storage tank full
surface fires, read below article
Cooling of adjacent tanks (within the
same dyke those are not on fire but exposing to radiation heat) must be ensured
by operating tank shell water spray system. this will help to minimize the vaporization
of oil and to reduce the risk of fire spread. It means that water cooling
system must be operated for both tanks, those on fire and adjacent tank without
fire too.
If the adjacent tank is floating roof
type, then it is important to apply firefighting foam on seal area of adjacent
tank as precaution to prevent ignition.
Burning surface of crude oil in tank develops
a heat wave which may travels downwards at a rate of 15 to 40 inches/hr.
Temperature of oil may reaches to 260 to 350 0C. When this heat wave reaches to
the tank bottom, where some settled water is generally present, it will cause a
violent “Boil-Over.”
Burning oil first erupts and then
falls, spreading even beyond the dyke of the tank. The columns of the flame can
be very widely spread at the base. The beginning of a boil over is indicated by
both increase in height and in brightness of the flames prior to actual
eruption of the boiling oil. In such scenario, all personnel including
firefighters must be immediately evacuated from that area.
In case of explosion in fixed roof tank, the semi-fixed foam
system is liable to get damaged and use of foam may get waste. Under such
circumstances, the only option is to apply the foam over the tank using HVLRM.
Storage tank firefighting - Fixed roof tank fire
(Light to Heavy Oils)
Prioritize the firefighting operation
in case of tank fire along with fire in dyke. Extinguish the dyke fire first by
applying medium expansion foam to reduce heat input to tank contents.
Operate tank shell cooling water spray
system or apply cooling water streams to tanks shell by use of ground water
monitors. Precautions should be taken to prevent the entry into the tank either
from run-off or from the water stream since it will destroy the foam blanket.
Apply firefighting foam inside the
tank either through fixed foam chamber connections or through other available
equipment.
Adjacent tanks cooling systems must be
operated to protect them from radiation heat exposure.
Observe the accumulation of
firefighting water in tank dyke, open tank dyke valves, to avoid flooding of
the tank dykes, if required. However, care should be taken to prevent spread of
spilled hydrocarbon.
Oil tank firefighting - Fixed roof tank fire
(FO tanks)
FO tanks are heated and operated at
temperatures above 1500C and therefore foam cannot be used in these
tanks. Precaution should also be taken while using water to cool the pipeline
so that no water enters the tank.
Start steam rings in case of failure of breather valve on top
of Tank only & combat the Fire using DCP Fire extinguisher. Stop heating
coil and reduce internal product temperature.
Extinguish the fire by operating DCP extinguishers (if fire is
less than 4 sq. mtr.). If involved fire area is more than 4 sq m. then fire
shall be extinguished in combination with DCP tender.
Use water monitors for water curtain, firefighting foam can be
used to fight the full surface tank fire.
Firefighting strategy for floating roof tank fire
Floating roof rim seal fires should be
extinguished by applying foam through fixed foam system or through foam branch
from the top platform.
Firefighting personnel should not go
down on the floating roof of a partially filled tank except in extreme circumstances.
In case it as absolutely necessary proper safety appliances such as safety
belt, lifeline, and fire suit must be used.
Actuate cooling water spray system, in
absence of this, apply water jet streams on the affected tank as well as
adjacent tanks as required. However, precaution should be taken to avoid water
stagnation on the floating roof since it may cause the float unbalanced.
Avoid directing heavy streams of water
into the flammable material of the roof edge. This may splash burning product
into the roof and increase the seriousness of the fire.
Open Tank dyke drain valves as
required to avoid flooding of the dyke area. Care should be taken not to spread
hydrocarbons to surrounding areas.
In case of full surface fire, use high capacity HVLRM from two
direction, if feasible, to cover the surface of burning liquid.
More details on full surface large diameter tank firefighting
strategies, you may read below article
Firefighting strategy and tactics for LPG fire
A large leakage of the LPG can form a
vapour cloud that can travel up to 1500m, while vapour from the open surfaces
of gasoline is not known to travel beyond 50m.
Approach the fire or gas leakage area from
upwind or crosswind. All fires (Process Heaters etc.), down wind of leak should
be put off or water curtain should be provided immediately.
Evacuate the area within the range of vapour
clouds as quickly as possible. In case, escaping LPG is not on fire, activate the
ROV to cut off the source of LPG. Water spray is effective in dispersing LPG
vapours. The spray stream should be directed across the normal vapour path.
Do not attempt to extinguish the LPG
fire unless the source of the leak cut off. A small LPG fire can be
extinguished by Dry chemical powder. The extinguishing agent should be directed
to the point of vapour release. Immediately start water spray on the leaking
LPG to avoid re-ignition.
Application of water spray to control LPG fire |
The best method is controlled burning of
leaking LPG as it prevents the formation of vapour cloud. The application of sufficient
quantity of water to keep the shell of the vessel and piping cool will allow
the fire to consume the products without risk of causing failure. It is
desirable that the leaks cannot be controlled after extinguishing fire and
wherever the leak can be controlled, attempt to extinguish the fire.
Firefighting strategy for LPG storage vessel fire
Do not extinguish the flame except by elimination
of fuel, as the accumulation of leaking gas forms a flammable vapour cloud and
increases the risk of explosion due to accidental ignition.
Stop the movement of the product in
and out of the tank by activating ROVs, etc.
Use the water spray system to cool the
shell of LPG vessel/ sphere, if this seems ineffective, use ground water
monitors to cool the vessels. Do not apply a solid jet directly on the shell of
the LPG vessel/sphere. Always make sure that water application must be in spray
mode.
In the event of a fire in the bottom
section, apply water spray through fixed/mobile water monitors to the piping
assembly/supporting structure. Water cooling should be carried out on the
adjacent storage vessels.
Water cooling on the affected vessel
should be continued even after the flame has been extinguished until all danger
of re-ignition of the hot surfaces or other sources has been eliminated.
Control burning of LPG and water spray for cooling |
Water spray protection for fire
fighters should be provided continuously as long as the danger of vapour cloud
persists.
If possible, pump water into the
vessel to float the flammable material above the leak point in the vessel/sphere.
This will extinguish the flames if the rate of water pumping exceeds the rate
of leakage (an attempt should only be made when competent to do so).
If a shell failure occurs below the
liquid level in the vessel/sphere and results in a leak that exceeds the
capacity of the water pumping facility, several solid streams of water should
be directed on the shell surrounding the leak.
Try to form a curtain of water spray
and maintain it until all flammable material i.e. LPG has been consumed and the
vessel has become gas-free by natural ventilation or by the addition of steam in
the vapour space of the sphere/vessel.
Before resuming the plant operations
after the end of firefighting, a gas test should be carried out in pits,
trenches or dykes where gas or heavy vapours could accumulate. Portable gas
detectors should be used to check for the presence of flammable gas. Similar
precautions and firefighting operation must be followed in the event of fire in
the LPG recovery Unit.
Secured the site for preserving the evidences of incident which may help during process safety incident investigation as part of process safety management
Firefighting strategy and techniques for hydrogen fire
The hydrogen flame is smoke-free and is not visible during the
day time. Necessary precaution should be taken during approaching the hydrogen
fire.
Hydrogen is extremely flammable and ignites with very less
energy (0.02 micro joule). The hydrogen fire turnout should be accompanied by
DCP tender/ engine. The
fire tender/engine must be parked in the upwind direction and firefighting
operation must be initiated from upwind /cross wind.
Actuate the deluge system manually for all adjacent as well as
H2 spheres which is on fire, if it is not
activated automatically.
Stop the transfer/ receive of H2 by shut down the compressor
& try to close all associated valves.
Operate fire water monitors for additional cooling &
shielding for firefighters. Use hand lines for the water curtain to protect
from radiation heat.
After fighting the fire, check the LEL at the point of
leakage. Continue to cool the sphere/compressor/ pipeline for an additional 30
minutes.
If the gas is leaking from the pipeline/source without burning
, measures must first be taken to stop
the leak, the water fog or spray is effectively used to disperse the explosive
mixture.
If the gas is already burning , it can be dangerous to
extinguish the flame and allow the gas to flow and burn , otherwise an
explosive mixture may form with air which , if ignited , can cause considerable
damage more important than if the original fire had been allowed to burn . The
best method to extinguish a gas fire is to stop the gas flow.
Firefighting method for natural gas fire
The appropriate extinguishing medium
is dry chemical powder (DCP) and the water is intended for cooling in spraying
mode. The Leak will form explosive mixtures which may travel to source of
ignition and cause a flash back. The compressor and piping may be exposed to
fire and may vent and release flammable gases through pressure relief devices. The
pipeline can explode when heated.
Gas fires must not be extinguished
unless the flow of gas is stopped.
Fire crews must wear a self-contained
breathing apparatus (SCBA) and a multilayer nomex suit.
Natural gas is lighter than air and
will vent upward, but special consideration should be paid to areas that may
trap or contain explosive concentrations, including areas of potential
migration underground or through structures.
Water spray can be used to cool
surrounding structures, including the compressor, pumps, pipeline, etc.
Firefighting strategy and tactics for rail wagon fire (Liquid Fire)
All the loading and unloading
operations must be suspended immediately in the affected area and isolate the respective
lines to minimize the risk of fire escalation.
Close the cover/ domes of all
unaffected wagons as much as possible.
Isolate the tanker/ wagon on fire from
other tankers those are not involved in the fire by using water spray through
hose lines.
Apply cooling water spray streams
through hose lines/fixed water monitors to the fire affected wagon, adjacent
wagons and other nearby equipment.
Remove unaffected wagons from the fire
areas as quickly as possible. Use a water screen to protect against radiation heat
for undertaking wagon removal or other operations.
Extinguish all ground fires before
attempting to extinguish the fire on tanker/ wagon.
After containing the fire on the wagon,
use firefighting foam or dry chemical powder to extinguish the fire. Water
spray should be continued for some time after the fire has been extinguished to
prevent re-ignition.
Salvage as much un-burnt liquid as
possible.
Firefighting strategy and tactics for rail wagon fire (LPG)
In the event of LPG wagons fire,
similar precautions to those of LPG storage vessels should be followed,
whenever possible. However, the DCP should only be used to extinguish the fire
and water for cooling.
Stop all pumping/loading operations.
Close block valves on pipelines to affected
wagon, LPG vessel/sphere as well as loading lines to gantry.
Isolate the burning LPG wagon from
other wagon trucks that are not yet involved in the fire.
Apply cooling water in spray mode from
fixed water monitors as well as hose lines to completely cool the wagon trucks.
Protect adjacent refinery equipment
and other tank trucks with a cooling water stream.
When the fire is contained using water
spray streams, apply DCP and foam to extinguish the flames. The cooling streams
must be maintained even after the flame has been extinguished until all danger
of re-ignition of the hot surfaces has been eliminated. Salvage as much un-burnt oil as
possible.
Firefighting techniques for sulphur fire
Evacuate the area and fight the fire
from a safe distance with self-contained breathing apparatus (SCBA) and full protective gear.
During a fire, irritating and highly
toxic gases may be generated by thermal decomposition or combustion.
Dust may present an explosion hazard
when exposed to heat or flame. Water spraying is effective in dispersing the
explosive dust cloud.
Flammable solid, can burn rapidly with
flaring effect, may re-ignite after the fire is extinguished. For large fires,
use water spray, fog or regular foam.
Do not disturb the fire by using a
water jet. CO2, DCP, Steam may be used to extinguish the fire in
molten sulphur.
Conclusion
Oil refinery and Petroleum industries inherently possess high risk of fire and
explosion due to processing and storing highly flammable material. In this
article we have discussed various firefighting method, strategies and
tactics to manage the fire and explosion hazards to save
the life and property. Process fires can be extinguished
effectively by ensuring adequate and effective firefighting strategies
and techniques, but the major control is to isolate the fuel supply. Crude
oil storage tank fire is challenging as possess boil over hazard and
required effective firefighting strategy with numerous resources.
Exchanger fires possess
explosion hazard and application of water may lead to thermal shock therefore
DCP/steam are the best firefighting media to extinguish the fire. Flammable
gas fire should not be attempted to extinguish as it may cause vapour
cloud and increase risk of vapour clod explosion.
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